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Förster coupling
Förster coupling is the resonant energy transfer between excitons within adjacent QD's (Quantum Dots). The first studies of Foerster were performed in the context of the sensitized luminescence of solids. Here, an excited sensitizer atom can transfer its excitation to a neighbouring acceptor atom, via an intermediate virtual photon. This same mechanism has also been shown to be responsible for exciton transfer between QD’s and within molecular systems and biosystems (though incoherently, as a mechanism for photosynthesis), all of which may be treated in a similar formulation. (See also Förster resonance energy transfer (FRET).)
==Introduction==
In the introductory lecture given by T. Förster,〔T. Förster, Discuss. Faraday Soc. 27, 7 (1959).〕 he considered the transfer of electronic excitation energy between otherwise well-separated atomic or molecular electronic systems, which exclude the trivial case of an excitation transfer that consists in the emission of one quantum of light by the first atom or molecule followed by re-absorption by the second one. It is only the non-radiative transfer of excitation occurring during the short lifetimes of excited electronic systems which he considered there.
The first observation of energy transfer was made by Cario and Franck (1922)〔Cario and Franck, Z. Physik, 1923, 17, 202.〕 in their classical experiments on sensitized fluorescence of atoms in the vapour phase. A mixture of mercury and thallium vapour, when irradiated with the light of the mercury resonance line, shows the emission spectra of both atoms. Since thallium atoms do not absorb the exciting light, they can get excited only indirectly by an excitation transfer from mercury atoms. A transfer by reabsorption is impossible here. Therefore, this transfer must be a non-radiative one with a mercury atom as the donor or sensitizer and the thallium atom as the acceptor. Unfortunately, in this case it cannot be decided whether the transfer occurs between distant atoms or during a normal collision or even in a labile molecule formed as an intermediate. This decision, however, was possible in similar cases, as in the mercury-sensitized fluorescence of sodium and in the mutual sensitization of the fluorescence of different mercury isotopes. In these cases, the transfer occurs over distances very much larger than those in normal collisional separations. Similar observations of sensitized fluorescence were made with molecular vapours and in solution.
Further experiments have shown that in this case the transfer occurs not over collisional distances but over the mean intermolecular distances of sensitizer and acceptor, corresponding to a concentration of 10−3 to 10−2M. This is demonstrated by the fact that sensitization occurs with similar half-value concentrations in solution of very different viscosities and even in organic glasses at low temperature. The possibility of the formation of a complex between sensitizer and acceptor molecules was excluded by the additivity of the absorption spectra and the different dependence on concentration to be expected in this case. It must be concluded, therefore, that excitation transfer of a non-trivial nature occurs over the mean distances between statistically distributed molecules which are about 40Å in this case. It differs from short-distance collisional transfer by its independence of solvent viscosity and from transfer within a molecular complex by the constancy of absorption spectra and the decrease in sensitizer fluorescence lifetime.
抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』
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